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Chemical substance record

Safrole

94-59-7C10H10O2162.188 g/mol

A member of the class of benzodioxoles that is 1,3-benzodioxole which is substituted by an allyl group at position 5. It is found in several plants, including black pepper, cinnamon and nutmeg, and is present in several essential oils, notably that of sassafras. It has insecticidal properties and has been used as a topical antiseptic. Although not thought to pose a significant carcinogenic risk to humans, findings of weak carcinogenicity in rats have resulted in the banning of its (previously widespread) use in perfumes and soaps, and as a food additive. — ChEBI

Safety references

Safety documents & references

1 indexed references
JP · NITE

Government GHS classification

R06-C-025-JNIOSH · FY2024

View classification

Find a product-specific SDS

Safety guides and government classification records are not a manufacturer’s SDS. Match supplier, product number, concentration, physical form, region and revision before using a document.

Identity & molecular properties

Source-linked values
CAS number94-59-7ChEBI ↗
Molecular formulaC10H10O2ChEBI ↗
Molar mass162.188 g/molChEBI ↗
Monoisotopic mass162.06808 DaChEBI ↗
Formal charge0ChEBI ↗
ChEBI identifierCHEBI:8994ChEBI ↗

Cross-source molecular data

PubChem
Molar mass162.18 g/molPubChem ↗
Exact mass162.068079557 DaPubChem ↗
Computed XLogP3PubChem ↗
Topological polar surface area (Ų)18.5PubChem ↗
H-bond donors0PubChem ↗
H-bond acceptors2PubChem ↗
Rotatable bonds2PubChem ↗

PubChem computed values are shown separately from the ChEBI record. An exact InChIKey match was used to connect the records. Molecular descriptors do not describe a supplied product’s purity, particle size or performance.

Names & structural identifiers

Copy any identifier
safrole
5-allyl-1,3-benzodioxole
ZMQAAUBTXCXRIC-UHFFFAOYSA-N
C=CCc1ccc2c(c1)OCO2
InChI=1S/C10H10O2/c1-2-3-8-4-5-9-10(6-8)12-7-11-9/h2,4-6H,1,3,7H2

Names & synonyms

5-allyl-1,3-benzodioxole

Names are supplied by ChEBI. Trade names and related synonyms may describe a broader product context.

Classification & relationships

ChEBI ontology

Roles recorded in ChEBI

insecticidemetaboliteflavouring agentplant metabolite

Database role annotations describe reported biological or chemical roles; they are not product approvals or recommendations for use.

Safety classification · Japan

NITE / Japanese government
Japan · FY2024 source classification
5-Allyl-1,3-benzodioxole · R06-C-025-JNIOSH
EndpointReported classification
CarcinogenicityCategory 1B

Selected source-reported endpoints. Other endpoints, rationales and conditions remain in the original classification. Missing or unlisted information does not mean non-hazardous. This is not a global classification or transport decision.

Read the original NITE classification

Mass ↔ amount of substance

Calculated from sourced mass
Equivalent amount
0.00616568 mol

Uses 162.188 g/mol from ChEBI. Assumes the substance described by this record; no purity or concentration correction is applied.

Elemental composition

Theoretical mass fractions
C
Carbon · 10 atoms
74.06%
O
Oxygen · 2 atoms
19.73%
H
Hydrogen · 10 atoms
6.22%

Calculated theoretical mass fractions from the reported formula and PubChem periodic-table atomic masses. These are not assay or purity results.

Research & patent references

Selected source associations
Safrole. ↗Report on carcinogens : carcinogen profiles · 2002 · PMID 15334724

Sources & record history

Checked 27 Sep 2026
EMBL-EBI ChEBI · CHEBI:8994

Release 255, 9 September 2026. ChEBI three-star (manually annotated) source entry. View original record ↗ · CC BY 4.0

NCBI PubChem · CID 5144 · retrieved 2026-09-27

PubCAS formats source data, connects references and computes explicitly labelled conversions. CAS cross-references are supplied by ChEBI; they do not constitute CAS verification or endorsement.